<scp>Chelation‐driven</scp> Regioselective 1,2‐Dearomatizations of <scp>N‐Aromatic</scp> Zwitterions

نویسندگان

چکیده

In this study, several dearomative reactions of N-aromatic zwitterions were carried out to determine the factors controlling site selectivity. A series organometallic species applied as nucleophiles for additions, which revealed that chelation between metal and nitrogen anion dominantly affected selectivity reaction in zwitterions. cascade process, involving addition followed by intermolecular cyclization, synthesize fused cyclic molecules was also demonstrated using ylides, selected capable substrates.

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ژورنال

عنوان ژورنال: Bulletin of The Korean Chemical Society

سال: 2021

ISSN: ['0253-2964', '1229-5949']

DOI: https://doi.org/10.1002/bkcs.12244